There are a few movies made from Babylon 5.
The first is Babylon 5: The Gathering
The second is Babylon 5: In the beginning
"The Gathering" was the pilot episode and "In the beginning" is the story in a nutshell. The other movies are (chronological): "Thirdspace", "River of Souls" and "A call to arms", but there isn't a DVD Version of those yet (there will be in a short period of time).
There are 5 seasons of Babylon 5, but there are at least one season (I don't know how many) of "Crusade". Crusade begins with the end of season 5 of B5. The Earth is infected with a nasty virus and is quarantined, a crew is going to look for a cure. There is also a spinnoff which has the name "The legend of the Rangers". I've never seen anything from that serie, so I don't know how or what.
If you want a more complete explanation of Babylon 5 and it's episodes, go here:
Lurker's guide to Babylon 5
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