It doesn't matter what order they cast Master/Slave in. They can be all jumbled up in any order, it's not important.
Why do you say it doesn't work? I think that the path bonuses to the master(s) aren't shown, but they do get the benefit.
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However, when I cast a self buff, it affects the slaves and the master.
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This means it's working. After the master casts the buff, you should find that the master has accrued much less fatigue than expected (though he will always get a certain amount just from his encumbrance), while all the slaves will have gained a bit of fatigue. You should also find that the master is able to cast spells with high path requirements that he wouldn't normally be able to cast.