Ich has it correct, and there's a distribution that is used precisely for this issue; it is the hypergeometric distribution.
Consider the following. A province in ME, by default, has a 40% chance of having a site. Let us assume no terrain modifiers are in place.
The number of sites that are available to find is given by the binomial distribution. The probabilities are:
0 - 0.1296
1 - 0.3456
2 - 0.3456
3 - 0.1536
4 - 0.0256
(Incidentally, this means that the average number of sites in a province with a per-site chance of 40% is 1.6.)
Therefore, if you have an unsearched province, and you cast Gnome Lore on that province, the probability that you find an earth site is the probability that there are X sites, and that there is at least one site among those X. That is:
[P(1 site) AND (Probability that site is Earth)] OR [P(2 sites) AND (Probability that the first site is earth OR Probability that the second site Earth)] OR [P(3 sites) AND (Probability that first site is Earth OR Probability that second site is Earth OR Probability of third site is Earth)] OR [P(4 sites) AND (Probability of first site is Earth OR Probability of second site is Earth OR Probability of third site being Earth OR Probability of fourth site being Earth). Since AND is mathematically multiplication, OR is mathematically addition, and P1 OR P2 OR P3 ... is equal to 1-P1*P2*P3..., we have, assuming equal chances of each type of site in this province:
(0.1296)(0) + (0.3456)(0.111) + (0.3456)(0.210) + (.1536)(0.298) + (0.0256)(0.376)
= 0.1663
or an 16.33% chance of finding an Earth site in that province.
Now, what happens if you have an Earth site in a province, and then cast Astral Probing on the same Province? Then the probability is:
P(2 sites)*(1-P(that site is not Earth) + P(3 sites)*(1-P(neither site remaining is Earth) + P(4 sites)*(1-P(none of the three sites remaining is Earth).
Or
0.3456*0.111 + 0.1536*0.210 + 0.0256*0.298
= 0.0783
Or an 7.83% chance of finding an Astral site in a province that already has another Earth site, _provided you did not search for the Earth site_. If you did, then it is 0.0876, or an 8.76% chance.
I hope this makes sense. If anyone wants other probabilities (especially the way this all changes if you select a different per-site probability), just let me know.